Earlier in the evening she had wowed the crowds at the premiere of her latest movie The Intern.
And Anne Hathaway managed to steal the show yet again as she left the after party with husband Adam Shulman in tow in London on Sunday.
The actress looked in fine form indeed as she sauntered out from posh Soho House with only her jewellery designer other half for company.
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Lovely pair: Anne Hathway and her handsome husband Adam Shulman at the The Intern after party in London on Sunday
The 32-year-old looked simply sensational in a fur coat, which covered the elegant black Jonathan Simkhai dress she had chosen to wear for her big night.
Handsome Adam meanwhile looked even hunkier than usual after making the brave fashion decision to wear a corduroy suit, which he paired with a black shirt, tie and leather shoes.
Earlier in the evening Anne had wowed the crowds at the premiere of her latest film, where even co-star Robert DeNiro was caught staring at her ample charms as they posed together on the red carpet.
The movie tells the fascinating tale of what happens when a 70-year-old retired executive decides he will fill his time by becoming the unpaid lackey to the founder and CEO of an e-commerce fashion company.
Causing a stir: But just as many admiring eyes will have been on her beefcake jewelery designer husband as they were on Anne
Un-fur-getable: She looked sensational in this rich blue coat which complimented her elegant earrings
Bringing up the rear: Adam was coming from behind the classy actress as she hopped into the waiting vehicle
Before marrying Adam, Anne was enveloped in an affair with real estate fraudster Raffaello Follieri, who she dated from 2004 until June 2008.
That very year he pleaded guilty to conspiracy, fraud and money laundering in connection with his business of buying property from the Catholic Church.
Speaking about her ex to David Letterman, she said: ‘I don’t want to go into the specifics but I will say that you do have to give me credit because as far as relationships crashing and burning goes, come on, I did pretty great. I mean, scorched that earth!’
Thankfully Anne, who served on the board of his charity but was never charged with any crimes, found happiness in the arms of future husband Adam.
And off they go: No doubt the glamour couple had plenty of things they wanted to do after leaving the party
Bob’s your uncle: In fact DeNiro looked like a man who had just struck the jackpot as he shamelessly stared at her chest at the premiere earlier in the evening
A class apart: The saucy starlet was oozing elegance as she posed on the red carpet in her black dress
Power pairing: Anne stars as a successful young businesswoman who hires Robert DeNiro’s character as her assistant in The Intern